据悉,ECHA于2013年12月10日更新了物品中高关注度物质(SVHC物质)的通报情况,主要涉及第1-8批SVHC物质,而物品中第9批SVHC物质的通报将于2013年12月20日截止。
在第1-8批138个SVHC物质中,ECHA只收到了32个SVHC物质在物品中的通报,其中以DEHP收到的通报最多,有103份。通报结果统计如下:
物质名称 | EC号 | CAS号 | 通报数量 |
邻苯二甲酸二(2-乙基已醇)酯 Bis(2-ethylhexyl)phthalate(DEHP) | 204-211-0 | 117-81-7 | 103 |
六溴环十二烷及其非对映异构体 Hexabromocyclododecane(HBCDD) and all major diastereoisomers identified: Alpha-hexabromocyclododecane Beta-hexabromocyclododecane Gamma-hexabromocyclododecane | 247-148-4, 221-695-9 | 25637-99-4, 3194-55-6 (134237-50-6)(134237-51-7)(134237-52-8) | 31 |
邻苯二甲酸二丁酯 Dibutyl phthalate(DBP) | 201-557-4 | 84-74-2 | 20 |
硅酸铝耐火陶瓷纤维(RCF) Aluminosilicate Refractory Ceramic Fibres are fibres covered by index number 650-017-00-8 in Annex VI, part 3, table 3.1 of Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures, and fulfil the three following conditions: a) oxides of aluminium and silicon are the main components present (in the fibres) within variable concentration ranges b) fibres have a length weighted geometric mean diameter less two standard geometric errors of 6 or less micrometres (µm) c) alkaline oxide and alkali earth oxide (Na2O+K2O+CaO+MgO+BaO) content less or equal to 18% by weight | / | / | 17 |
硼酸 Boric acid | 233-139-2, 234-343-4 | 10043-35-3, 11113-50-1 | 13 |
邻苯二甲酸二异丁酯 Diisobutyl phthalate | 201-553-2 | 84-69-5 | 10 |
无水四硼酸钠 Disodium tetraborate, anhydrous | 215-540-4 | 1303-96-4, 1330-43-4, 12179-04-3 | 10 |
偶氮二甲酰胺 Diazene-1,2-dicarboxamide(C,C'-azodi(formamide)) | 204-650-8 | 123-77-3 | 7 |
十溴二苯醚 Bis(pentabromophenyl) ether (decabromodiphenyl ether; DecaBDE) | 214-604-9 | 1163-19-5 | 6 |
C10-13短链氯化石蜡 Alkanes, C10-13, chloro (Short Chain Chlorinated Paraffins) | 287-476-5 | 85535-84-8 | 6 |
四氧化三铅 Orange lead (lead tetroxide) | 215-235-6 | 1314-41-6 | 4 |
C.I. 颜料黄34 Lead sulfochromate yellow(C.I. Pigment Yellow 34) | 215-693-7 | 1344-37-2 | 4 |
钛酸铅锆 Lead titanium zirconium oxide | 235-727-4 | 12626-81-2 | 4 |
硫酸铅铬钼红(C.I. 颜料红104) Lead chromate molybdate sulphate red(C.I. Pigment Red 104) | 235-759-9 | 12656-85-8 | 4 |
邻苯二甲酸丁芐酯 Benzyl butyl phthalate(BBP) | 201-622-7 | 85-68-7 | 4 |
氧化锆硅酸铝耐火陶瓷纤维(Zr-RCF) Zirconia Aluminosilicate Refractory Ceramic Fibres are fibres covered by index number 650-017-00-8 in Annex VI, part 3, table 3.1 of Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures, and fulfil the three following conditions: a) oxides of aluminium, silicon and zirconium are the main components present (in the fibres) within variable concentration ranges b) fibres have a length weighted geometric mean diameter less two standard geometric errors of 6 or less micrometres (µm). c) alkaline oxide and alkali earth oxide (Na2O+K2O+CaO+MgO+BaO) content less or equal to 18% by weight | / | / | 2 |
磷酸三(2-氯乙基)酯 Tris(2-chloroethyl)phosphate | 204-118-5 | 115-96-8 | 2 |
N,N-二甲基乙酰胺(DMAC) N,N-dimethylacetamide | 204-826-4 | 127-19-5 | 2 |
三氧化二硼 Diboron trioxide | 215-125-8 | 1303-86-2 | 2 |
黄丹 Lead monoxide(lead oxide) | 215-267-0 | 1317-36-8 | 2 |
高温煤沥青 Pitch, coal tar, high temp. | 266-028-2 | 65996-93-2 | 2 |
2,4 -二硝基甲苯 2,4-Dinitrotoluene | 204-450-0 | 121-14-2 | 2 |
1-甲基-2-吡咯烷酮 1-Methyl-2-pyrrolidone | 212-828-1 | 872-50-4 | 2 |
铬酸铅 Lead chromate | 231-846-0 | 7758-97-6 | 2 |
二碱式亚磷酸铅 Trilead dioxide phosphonate | 235-252-2 | 12141-20-7 | 1 |
三丁基氧化锡 Bis(tributyltin)oxide(TBTO) | 200-268-0 | 56-35-9 | 1 |
三氯乙烯 Trichloroethylene | 201-167-4 | 79-01-6 | 1 |
乙二醇二甲醚 1,2-dimethoxyethane; ethylene glycol dimethyl ether(EGDME) | 203-794-9 | 110-71-4 | 1 |
乙二醇乙醚醋酸酯 2-Ethoxyethyl acetate | 203-839-2 | 111-15-9 | 1 |
对特辛基苯酚 4-(1,1,3,3-tetramethylbutyl)phenol | 205-426-2 | 140-66-9 | 1 |
五氧化二砷 Diarsenic pentaoxide | 215-116-9 | 1303-28-2 | 1 |
甲基六氢苯酐、4-甲基六氢苯酐、甲基六氢化邻苯二甲酸酐、3-甲基六氢苯二甲酯酐,包括这4种物质左旋、右旋单体以及相应物质所有左、右旋的组合 Hexahydromethylphthalic anhydride [1] Hexahydro-4-methylphthalic anhydride [2] Hexahydro-1-methylphthalic anhydride [3] Hexahydro-3-methylphthalic anhydride [4] [The individual isomers [2], [3] and [4] (including their cis- and trans- stereo isomeric forms) and all possible combinations of the isomers [1] are covered by this entry] | 247-094-1, 243-072-0, 256-356-4, 260-566-1 | 25550-51-0, 19438-60-9, 48122-14-1, 57110-29-9 | 1 |
SVHC即高关注度物质,英文全称为Substances of Very High Concern。根据欧盟REACH法规第57条,高关注度物质共有以下几种:
第1类和第2类致癌,致畸和具有生殖毒性的物质,即CMR1类和2类物质;
持久性、生物累积性和毒性的物质,即PBT物质;
高持久性、高生物累积性的物质,即 vPvB物质;
具有内分泌干扰特性,或具持久性、生物累积性和毒性,或具高持久性、高生物累积性但不符合2、3两项标准,同时有科学证据证明对人类或环境引起严重影响的物质,即同等关注物质。
根据REACH法规第7条第2款:如果物品中含有SVHC物质,且满足以下两个条件时,生产商或进口商需根据法规第7条第4款向欧洲化学品管理局(ECHA)进行通报,且通报内容和格式必须符合相关通报要求:
高关注物质在物品中的含量超过1吨/年;
高关注物质在物品中的质量百分浓度超过0.1%。